Nonreactive molecular collisions
In nonreactive collisions, particles collide somewhere between elasticaly and
inelastically. Elastic collisions would invovle no exchange of energy
between the two colliding particles. Inelastic collisions do exchange
energy, therefore some degrees of freedom lose or gain energy during an
inelastic collision. In the total energy terms
"E",
e,t,r, and
v stand
for electronic, translational, rotational, and vibrational. Here is a
diagram of the process:
After the inelastic collsion, the density of each of these states changes. For example, the methane molecule could lose some translational energy to one of the normal vibrating ammonia modes.
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